![]() The bankruptcy court deemed such a balancing appropriate because SL Green was both a creditor and equity owner of the Debtors, and had structured its equity investment, and control over PWM’s ability to file for bankruptcy, primarily to protect its creditor status. However, the bankruptcy court considered the public policy of promoting access to bankruptcy relief and balanced the right of a business to file for bankruptcy against any limits in its governing agreements on the corporate authority to do so. The bankruptcy court did not dispute that the relevant limited liability company agreement required SL Green to consent to a bankruptcy filing of one of the Debtors and noted that, generally, a corporate entity’s action contravening the authority in its constituent agreements is void. ![]() In what it called a “close decision,” the bankruptcy court denied the motion to dismiss. SL Green’s motion to dismiss highlights a tension, addressed in a series of bankruptcy cases over the last decade, between two fundamental principles of bankruptcy law: (1) an entity must have proper corporate authority under its organizational documents to seek bankruptcy relief and (2) prepetition agreements that prospectively prohibit bankruptcy filings may be void as against public policy, depending on the facts and circumstances in which they are invoked. SL Green also argued that the solvent Debtors were not experiencing financial distress and had filed for chapter 11 protection (and moved to reject the management agreement for 245 Park) as leverage in a two-party dispute with SL Green, and thus had not filed for bankruptcy in good faith. SL Green argued that HNA improperly empowered two newly appointed Independent Agents of the Debtors to authorize the bankruptcy filing and, more importantly, that the limited liability company agreement governing the Debtor in which SL Green was a minority member specifically required the SL Green member’s consent to authorize a bankruptcy filing, which consent was not obtained. SL Green moved to dismiss all the chapter 11 filings on two grounds: the bankruptcy petitions were not properly authorized and were not filed in good faith. HNA, a Chinese real estate conglomerate, is the majority owner of the Debtors and of the entity which favored a chapter 11 filing for the Debtors. (collectively with its affiliates, “SL Green”) was the property manager at 245 Park, a minority owner in one Debtor, and a mezzanine lender to another. The Debtors hold direct or indirect interests in two real properties-245 Park Avenue in New York City (“245 Park”) and 181 West Madison Street in Chicago (the “Chicago Property”). ![]() On October 31, 2021, PWM Property Management LLC and eight of its affiliates (collectively, “PWM” or the “Debtors”) filed chapter 11 petitions in the United States Bankruptcy Court for the District of Delaware. ![]()
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3/1/2024 0 Comments Free home landscape design app![]() ![]() You can select the exact dimensions of your yard, drag and drop over 200 outdoor design items, and instantly see the result in 3D. Home Design 3D Outdoor & Garden is a simple, intuitive and comprehensive app that boasts all the features of the original Home Design 3D but this time for outdoor spaces like yards and gardens. It has excellent reviews from those who have installed it. Home Outside is one of the deepest and most customizable landscapes and home design apps on the market right now. You can also import a photo as the background so you can design a digital image of your property plan or layout. There are many different tools available within the app including a sketch tool that allows users to draw garden beds and other free-form shapes and a map tool that allows you to import an image of your home from Google Maps. The tap-and-drag functionality is easy to use and you can choose from over 700 elements in 29 different palettes to design your dream home and yard. Home Outside is a great landscape design and planning app that really does make landscape design available and accessible for anyone. Home Outside: Landscape Design for Everyone – $2.99 The Houzz app and website are highly respected and very popular. In addition to these great features, the Houzz editorial staff and design experts keep you up to date on the latest industry trends, news, and advice in their articles and newsletters. ![]() You can also use the app to find a home improvement professional like contractors and repair professionals. The Houzz app features verified product reviews as well as more than 16 million high-res photos of both interiors and exteriors to give you great landscape design ideas for your home. While the app is most commonly used for interior decorating, it also has an extensive outdoor decorating and designing section that can help you create your dream yard. It’s a great resource for finding a contractor and designing your perfect home, both inside and out. ![]() Houzz is one of the most popular landscape design apps and websites right now. Reviews by users are mixed but mostly fair to good. You will find it to be one of the best landscape design apps. Whether you are a casual or serious home gardener, seasoned or novice landscaper, you can get all the information you need on any plant you have your eye on and are considering planting on your property. It is a comprehensive database of information on more than 26,000 plants and 21,000 photos. One of the top apps to assist you with your plant landscaping in your garden is Landscaper’s Companion. Landscaper’s Companion – Plant & Gardening Guide $9.99 Reviews for iScape are fair, but most users have rated it as excellent. The free version is meant to give you a chance to test drive, so to speak, in case you would want the paid version. This is considered one of the best landscape design apps. It is user friendly and has features that include a virtual pen, the ability to insert objects, and more. From there, you can create your vision by designing over the image within the app. It is easy to use and requires you to take a photo of your garden or front yard with your phone’s camera. IScape is useful in helping you get a better idea about what landscaping design would work well for you. These are great if you are interested in getting excellent landscape ideas, and as a result, you can show your ideas to a landscape design contractor who can bring your designs to life. If you are having difficulty coming up with ideas, you can benefit from some landscape design tips.įor inspiration, you can look to the best landscape design apps available for the iPhone or Android smartphones. Smartphone Apps Provide Inspiration for Landscape Design IdeasĪs a homeowner, you might want to shake things up outdoors in your yard or front lawn with some great landscape design projects. ![]() ![]() ![]() In this case, while asking families to describe situations about the patient’s progress, nurses need to ask them to describe how they dealt with similar situations in the past to assess the successful coping mechanisms available to the family. In this case, identifying the family’s history and child-rearing patterns over generations can help engage families to provide their stories. Ideally, genograms are best developed with families over different meetings to present an accurate picture of the family.Ī genogram record organizes and displays family information that may be sensitive and elicit a range of emotions from the family members. It is a format for drawing a family tree displaying the family information for at least three or more generations. The genogram is a tool to collect information on the family’s structure and caregiving patterns over time. In this case, genograms and ecomaps can help gain information about context, perspective, and frame of reference for families.(ecomaps and genograms) Genograms in Family Assessment However, health providers must develop the necessary skills to understand a patient’s family frame of reference to make accurate decisions about the patient’s healthcare. When working with families, there is often limited information and understanding of the family’s frame of reference. ![]() In this case, family ecomaps and genograms are essential tools that can help identify a person’s family history to identify underlying factors that may affect their health outcomes. However, health is highly influenced by a range of factors, such as family genetics, community lifestyle, and medical histories, which can lead to rapid changes in an individual. But unfortunately, most people feel that health is a highly controlled factor that can be controlled through a healthy lifestyle and regular checkups. Health is one of the most significant aspects of today’s society. 7 Working On an Assignment With Similar Concepts Or Instructions? Background of Ecomaps and Genograms ![]() 3/1/2024 0 Comments Absolute entropy data table![]() ![]() which absolute values cannot be assigned. ![]() Furthermore, we show some application examples for the calculation of free energy differences in typical chemical reactions.≥ 0\). Use data from Table 13.8 and Figure 13-10 to estimate the temperature at which. Comprehensive tests indicate a relatively strong variation of the conformational entropy on the underlying level of theory for typical drug molecules, inferring the complex potential energy surfaces as the main source of error. Because the entropy of a substance depends on the amount of substance, the pressure, and the temperature, it is convenient to describe the entropy of a substance in terms of S m °, its standard molar entropy, i.e., as the entropy of 1 mol of substance at the standard pressure of 1 atm (101.3 kPa) and given temperature. Even for the hardship case of extremely flexible linear alkanes (C 14H 30–C 16H 34), errors are only about 3 cal mol −1 K −1. Using a standard-state enthalpy of formation and absolute entropy data table, we find the following information: Compound AHP(kJ/mol) S(J/mol-K) NHANO:(s) NHA (aq) NO3 (aq) -365.56 -132.51 -205.0 151.08 113.4 146.4 Calculate AH and AS for the following reaction: NH4NO:(s)-NH (aq)+ NOs (aq) Use the results of this calculation to determine the value of G for this reaction at 25C, and. Using a table of bond energies determine the molar. (c) Calculate the standard absolute entropy, S, per mole of O2(g). Extensive tests of the protocol with the two standard DFT approaches B97-3c and B3LYP-D3 reveal an unprecedented accuracy with mean deviations <1 cal mol −1 K −1 (about <1–2%) for the total gas phase molecular entropy of medium-sized molecules. In the reaction N2(g) + 3H2(g) to 2NH3(g) delta H -92.4 kJ/mol The absolute entropy values. 25) Use data table H and S to calculate 4Gran in kJ/mol at 55C for the. Question: For the following reaction: 2 NO2(g) N2O4(g) Using a standard-state enthalpy of Formation and absolute entropy data table, we find the following information: Compound AHf(kJ/mol) S(J/mol.K) NO2(g) 33.18 240.06 N204(9) 9.16 304.29 Determine the value of AG', and predict the spontaneity of this for this reaction at 25C. Add a comment Your Answer Thanks for contributing an answer to Engineering Stack Exchange Please be sure to answer the question. ![]() not the 'absolute' entropy endgroup Fennekin. For the first time, variations of the ro-vibrational entropy over the CE are consistently accounted-for through a Boltzmann-population average. begingroup by that you will get change in entropy. Using a standard-state enthalpy of formation and absolute entropy data table, we find the following information: Compound(kJ/mol) S (J/mol-K) ) 0 130.68. Anharmonic effects are included through the modified rigid-rotor-harmonic-oscillator (msRRHO) approximation and the Gibbs–Shannon formula for extensive conformer ensembles (CEs), which are generated by a metadynamics search algorithm and are extrapolated to completeness. for the following reaction and decide in which direction each of these factors will drive the reaction. The scheme is systematically expandable and can be integrated seamlessly with continuum-solvation models. We propose a fully-automated composite scheme for the accurate and numerically stable calculation of molecular entropies by efficiently combining density-functional theory (DFT), semi-empirical methods (SQM), and force-field (FF) approximations. ![]() ![]() Big tip: Be sure and seal the texture with Kilz.” Of course, we mud, taped and textured all the walls. Rebecca described her vision, “I wanted a rustic log home and the interior is done in wood paneling and lots of glazed walls in earth tones, which I did myself. That’s why manufactured homes are so great – you can actually afford to make changes to the home after you buy it! ![]() It was a fine home but it wasn’t their style. Here’s a photo of the kitchen before the McCormack’srustic cabin manufactured home remodel. If you think the exterior remodel was amazing, just wait till you see the interior! ![]() Rustic cabin Manufactured Home Remodel – Interior Looking for more inspiration to remodel the exterior of your manufactured home? Check out this complete double wide transformation. The back of the home is just as gorgeous as the front. Porch fans and gorgeous seating areas complete the log cabin exterior remodel. The log siding was trimmed in a darker wood that highlights the new windows. He installed a sprinkler system and laid river rock in the circle drives. The exterior was completely wrapped in log siding, the deck was transformed into a covered porch, rock skirting was installed, a garage was added to the side of the home, and lots of beautiful landscaping was added. Here’s what the back of the home looked like before the log cabin remodel.Īfter the Rustic Cabin Manufactured Home Remodel The front exterior had already been updated with shingled vinyl siding and a new deck but the couple had a more traditional log cabin vision and they absolutely nailed it! ” My favorite room is probably the kitchen.”īefore the Rustic Cabin Manufactured Home Remodel.Rustic cabin Manufactured Home Remodel – Interior.After the Rustic Cabin Manufactured Home Remodel.Before the Rustic Cabin Manufactured Home Remodel. ![]() ![]() ![]() ![]() However, IUPAC recommends that the numbers 1 through 18 be used, and these labels are more common. In the United States, the labels traditionally were numerals with capital letters. Groups are labeled at the top of each column. The elements are arranged in seven horizontal rows, called periods or series, and 18 vertical columns, called groups. Each box represents an element and contains its atomic number, symbol, average atomic mass, and (sometimes) name. A modern periodic table arranges the elements in increasing order of their atomic numbers and groups atoms with similar properties in the same vertical column (Figure 2). The modern statement of this relationship, the periodic law, is as follows: the properties of the elements are periodic functions of their atomic numbers. (credit a: modification of work by Serge Lachinov credit b: modification of work by “Den fjättrade ankan”/Wikimedia Commons)īy the twentieth century, it became apparent that the periodic relationship involved atomic numbers rather than atomic masses. (a) Dimitri Mendeleev is widely credited with creating (b) the first periodic table of the elements. Although Mendeleev and Meyer had a long dispute over priority, Mendeleev’s contributions to the development of the periodic table are now more widely recognized (Figure 1).įigure 1. The discoveries of gallium (1875) and germanium (1886) provided great support for Mendeleev’s work. But Mendeleev went one step further than Meyer: He used his table to predict the existence of elements that would have the properties similar to aluminum and silicon, but were yet unknown. Both published tables with the elements arranged according to increasing atomic mass. Fluorine (F), chlorine (Cl), bromine (Br), and iodine (I) also exhibit similar properties to each other, but these properties are drastically different from those of any of the elements above.ĭimitri Mendeleev in Russia (1869) and Lothar Meyer in Germany (1870) independently recognized that there was a periodic relationship among the properties of the elements known at that time. For example: Li, Na, and K are much more reactive than are Ca, Sr, and Ba Li, Na, and K form compounds with oxygen in a ratio of two of their atoms to one oxygen atom, whereas Ca, Sr, and Ba form compounds with one of their atoms to one oxygen atom. However, the specific properties of these two groupings are notably different from each other. A second grouping includes calcium (Ca), strontium (Sr), and barium (Ba), which also are shiny, good conductors of heat and electricity, and have chemical properties in common. One such grouping includes lithium (Li), sodium (Na), and potassium (K): These elements all are shiny, conduct heat and electricity well, and have similar chemical properties. Identify metals, nonmetals, and metalloids by their properties and/or location on the periodic tableĪs early chemists worked to purify ores and discovered more elements, they realized that various elements could be grouped together by their similar chemical behaviors.Predict the general properties of elements based on their location within the periodic table.State the periodic law and explain the organization of elements in the periodic table.\)īy the end of this section, you will be able to: ![]() |
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