![]() The bankruptcy court deemed such a balancing appropriate because SL Green was both a creditor and equity owner of the Debtors, and had structured its equity investment, and control over PWM’s ability to file for bankruptcy, primarily to protect its creditor status. However, the bankruptcy court considered the public policy of promoting access to bankruptcy relief and balanced the right of a business to file for bankruptcy against any limits in its governing agreements on the corporate authority to do so. The bankruptcy court did not dispute that the relevant limited liability company agreement required SL Green to consent to a bankruptcy filing of one of the Debtors and noted that, generally, a corporate entity’s action contravening the authority in its constituent agreements is void. ![]() In what it called a “close decision,” the bankruptcy court denied the motion to dismiss. SL Green’s motion to dismiss highlights a tension, addressed in a series of bankruptcy cases over the last decade, between two fundamental principles of bankruptcy law: (1) an entity must have proper corporate authority under its organizational documents to seek bankruptcy relief and (2) prepetition agreements that prospectively prohibit bankruptcy filings may be void as against public policy, depending on the facts and circumstances in which they are invoked. SL Green also argued that the solvent Debtors were not experiencing financial distress and had filed for chapter 11 protection (and moved to reject the management agreement for 245 Park) as leverage in a two-party dispute with SL Green, and thus had not filed for bankruptcy in good faith. SL Green argued that HNA improperly empowered two newly appointed Independent Agents of the Debtors to authorize the bankruptcy filing and, more importantly, that the limited liability company agreement governing the Debtor in which SL Green was a minority member specifically required the SL Green member’s consent to authorize a bankruptcy filing, which consent was not obtained. SL Green moved to dismiss all the chapter 11 filings on two grounds: the bankruptcy petitions were not properly authorized and were not filed in good faith. HNA, a Chinese real estate conglomerate, is the majority owner of the Debtors and of the entity which favored a chapter 11 filing for the Debtors. (collectively with its affiliates, “SL Green”) was the property manager at 245 Park, a minority owner in one Debtor, and a mezzanine lender to another. The Debtors hold direct or indirect interests in two real properties-245 Park Avenue in New York City (“245 Park”) and 181 West Madison Street in Chicago (the “Chicago Property”). ![]() On October 31, 2021, PWM Property Management LLC and eight of its affiliates (collectively, “PWM” or the “Debtors”) filed chapter 11 petitions in the United States Bankruptcy Court for the District of Delaware. ![]()
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![]() ![]() In the earlier 2010s, in Runet spread pictures and videos with a little lady of ten. It is usually the previous, should not really create me a guy introverted, lonely. Her other ambitions include getting an education and getting a psychiatrist. Lagu Lagu India Shahrukh Khan Térbaru 2014 - Sukaa Gratis Video Search Motor - Cari dan download video yang kamu suká di bikinasik. Masha Babko Siberian Mouse 1St Studio Torrent Download Video Yang In Nov 2011 photographer pedophile Sergey Kropotkin detained. Masha Babko Siberian Mouse 1St Studio Torrent Torrent Files Are Masha Babko Siberian Mouse 1St Studio Torrent Torrent Files Are.Masha Babko Siberian Mouse 1St Studio Torrent Download Video Yang.Siberia is considered a modelling reservoir, thanks to ethnic mixing.Ī little powder, and barely pubescent girls turn into femmes fatales.Ī fashion show after the casting call allows scouts to observe the models in real conditions.įor many young women from small villages, modelling offers a chance to travel and earn a lot of money. Her ticket to Paris is within reach.įor the ones left behind, the rejection is often brutal.ġ5-year-old Kristina Churina just graduated from Novosibirsk’s modelling school and has caught the attention of the Paris agency.īut Stephane Hababou hesitates about Kristina: “If she loses weight, we’ll see see how she changes.” Petersburg.Īnna discovers 30 to 40 fresh and interesting faces every month.Īnastasia Akhmameteva catches the eye of Stephane Hababou. Stephane Hababou, from the Marilyn agency in Paris, has come to Siberia to find the most promising beauties before his rivals do.Īnna Yuzhakova (centre), herself a former model, visits Siberia four times a year on behalf of the Noah modeling agency in St. With hips measuring 93 centimetres (36.6 inches), Marina Korotkova is considered “a little fat.” Maximum hips: 90 centimetres (35.4 inches).Ĭasting calls are open to all and attract about 60 hopeful young women every time they are held. Minimum height: 172 centimetres (5 feet, 6 inches). But in the world of fashion, the region is famous for being home to the most beautiful women in the world. Siberia is known around the world for its frigid temperatures. ![]()
3/1/2024 0 Comments Free home landscape design app![]() ![]() You can select the exact dimensions of your yard, drag and drop over 200 outdoor design items, and instantly see the result in 3D. Home Design 3D Outdoor & Garden is a simple, intuitive and comprehensive app that boasts all the features of the original Home Design 3D but this time for outdoor spaces like yards and gardens. It has excellent reviews from those who have installed it. Home Outside is one of the deepest and most customizable landscapes and home design apps on the market right now. You can also import a photo as the background so you can design a digital image of your property plan or layout. There are many different tools available within the app including a sketch tool that allows users to draw garden beds and other free-form shapes and a map tool that allows you to import an image of your home from Google Maps. The tap-and-drag functionality is easy to use and you can choose from over 700 elements in 29 different palettes to design your dream home and yard. Home Outside is a great landscape design and planning app that really does make landscape design available and accessible for anyone. Home Outside: Landscape Design for Everyone – $2.99 The Houzz app and website are highly respected and very popular. In addition to these great features, the Houzz editorial staff and design experts keep you up to date on the latest industry trends, news, and advice in their articles and newsletters. ![]() You can also use the app to find a home improvement professional like contractors and repair professionals. The Houzz app features verified product reviews as well as more than 16 million high-res photos of both interiors and exteriors to give you great landscape design ideas for your home. While the app is most commonly used for interior decorating, it also has an extensive outdoor decorating and designing section that can help you create your dream yard. It’s a great resource for finding a contractor and designing your perfect home, both inside and out. ![]() Houzz is one of the most popular landscape design apps and websites right now. Reviews by users are mixed but mostly fair to good. You will find it to be one of the best landscape design apps. Whether you are a casual or serious home gardener, seasoned or novice landscaper, you can get all the information you need on any plant you have your eye on and are considering planting on your property. It is a comprehensive database of information on more than 26,000 plants and 21,000 photos. One of the top apps to assist you with your plant landscaping in your garden is Landscaper’s Companion. Landscaper’s Companion – Plant & Gardening Guide $9.99 Reviews for iScape are fair, but most users have rated it as excellent. The free version is meant to give you a chance to test drive, so to speak, in case you would want the paid version. This is considered one of the best landscape design apps. It is user friendly and has features that include a virtual pen, the ability to insert objects, and more. From there, you can create your vision by designing over the image within the app. It is easy to use and requires you to take a photo of your garden or front yard with your phone’s camera. IScape is useful in helping you get a better idea about what landscaping design would work well for you. These are great if you are interested in getting excellent landscape ideas, and as a result, you can show your ideas to a landscape design contractor who can bring your designs to life. If you are having difficulty coming up with ideas, you can benefit from some landscape design tips.įor inspiration, you can look to the best landscape design apps available for the iPhone or Android smartphones. Smartphone Apps Provide Inspiration for Landscape Design IdeasĪs a homeowner, you might want to shake things up outdoors in your yard or front lawn with some great landscape design projects. ![]() ![]() ![]() In this case, while asking families to describe situations about the patient’s progress, nurses need to ask them to describe how they dealt with similar situations in the past to assess the successful coping mechanisms available to the family. In this case, identifying the family’s history and child-rearing patterns over generations can help engage families to provide their stories. Ideally, genograms are best developed with families over different meetings to present an accurate picture of the family.Ī genogram record organizes and displays family information that may be sensitive and elicit a range of emotions from the family members. It is a format for drawing a family tree displaying the family information for at least three or more generations. The genogram is a tool to collect information on the family’s structure and caregiving patterns over time. In this case, genograms and ecomaps can help gain information about context, perspective, and frame of reference for families.(ecomaps and genograms) Genograms in Family Assessment However, health providers must develop the necessary skills to understand a patient’s family frame of reference to make accurate decisions about the patient’s healthcare. When working with families, there is often limited information and understanding of the family’s frame of reference. ![]() In this case, family ecomaps and genograms are essential tools that can help identify a person’s family history to identify underlying factors that may affect their health outcomes. However, health is highly influenced by a range of factors, such as family genetics, community lifestyle, and medical histories, which can lead to rapid changes in an individual. But unfortunately, most people feel that health is a highly controlled factor that can be controlled through a healthy lifestyle and regular checkups. Health is one of the most significant aspects of today’s society. 7 Working On an Assignment With Similar Concepts Or Instructions? Background of Ecomaps and Genograms ![]() 3/1/2024 0 Comments Absolute entropy data table![]() ![]() which absolute values cannot be assigned. ![]() Furthermore, we show some application examples for the calculation of free energy differences in typical chemical reactions.≥ 0\). Use data from Table 13.8 and Figure 13-10 to estimate the temperature at which. Comprehensive tests indicate a relatively strong variation of the conformational entropy on the underlying level of theory for typical drug molecules, inferring the complex potential energy surfaces as the main source of error. Because the entropy of a substance depends on the amount of substance, the pressure, and the temperature, it is convenient to describe the entropy of a substance in terms of S m °, its standard molar entropy, i.e., as the entropy of 1 mol of substance at the standard pressure of 1 atm (101.3 kPa) and given temperature. Even for the hardship case of extremely flexible linear alkanes (C 14H 30–C 16H 34), errors are only about 3 cal mol −1 K −1. Using a standard-state enthalpy of formation and absolute entropy data table, we find the following information: Compound AHP(kJ/mol) S(J/mol-K) NHANO:(s) NHA (aq) NO3 (aq) -365.56 -132.51 -205.0 151.08 113.4 146.4 Calculate AH and AS for the following reaction: NH4NO:(s)-NH (aq)+ NOs (aq) Use the results of this calculation to determine the value of G for this reaction at 25C, and. Using a table of bond energies determine the molar. (c) Calculate the standard absolute entropy, S, per mole of O2(g). Extensive tests of the protocol with the two standard DFT approaches B97-3c and B3LYP-D3 reveal an unprecedented accuracy with mean deviations <1 cal mol −1 K −1 (about <1–2%) for the total gas phase molecular entropy of medium-sized molecules. In the reaction N2(g) + 3H2(g) to 2NH3(g) delta H -92.4 kJ/mol The absolute entropy values. 25) Use data table H and S to calculate 4Gran in kJ/mol at 55C for the. Question: For the following reaction: 2 NO2(g) N2O4(g) Using a standard-state enthalpy of Formation and absolute entropy data table, we find the following information: Compound AHf(kJ/mol) S(J/mol.K) NO2(g) 33.18 240.06 N204(9) 9.16 304.29 Determine the value of AG', and predict the spontaneity of this for this reaction at 25C. Add a comment Your Answer Thanks for contributing an answer to Engineering Stack Exchange Please be sure to answer the question. ![]() not the 'absolute' entropy endgroup Fennekin. For the first time, variations of the ro-vibrational entropy over the CE are consistently accounted-for through a Boltzmann-population average. begingroup by that you will get change in entropy. Using a standard-state enthalpy of formation and absolute entropy data table, we find the following information: Compound(kJ/mol) S (J/mol-K) ) 0 130.68. Anharmonic effects are included through the modified rigid-rotor-harmonic-oscillator (msRRHO) approximation and the Gibbs–Shannon formula for extensive conformer ensembles (CEs), which are generated by a metadynamics search algorithm and are extrapolated to completeness. for the following reaction and decide in which direction each of these factors will drive the reaction. The scheme is systematically expandable and can be integrated seamlessly with continuum-solvation models. We propose a fully-automated composite scheme for the accurate and numerically stable calculation of molecular entropies by efficiently combining density-functional theory (DFT), semi-empirical methods (SQM), and force-field (FF) approximations. ![]() ![]() Big tip: Be sure and seal the texture with Kilz.” Of course, we mud, taped and textured all the walls. Rebecca described her vision, “I wanted a rustic log home and the interior is done in wood paneling and lots of glazed walls in earth tones, which I did myself. That’s why manufactured homes are so great – you can actually afford to make changes to the home after you buy it! ![]() It was a fine home but it wasn’t their style. Here’s a photo of the kitchen before the McCormack’srustic cabin manufactured home remodel. If you think the exterior remodel was amazing, just wait till you see the interior! ![]() Rustic cabin Manufactured Home Remodel – Interior Looking for more inspiration to remodel the exterior of your manufactured home? Check out this complete double wide transformation. The back of the home is just as gorgeous as the front. Porch fans and gorgeous seating areas complete the log cabin exterior remodel. The log siding was trimmed in a darker wood that highlights the new windows. He installed a sprinkler system and laid river rock in the circle drives. The exterior was completely wrapped in log siding, the deck was transformed into a covered porch, rock skirting was installed, a garage was added to the side of the home, and lots of beautiful landscaping was added. Here’s what the back of the home looked like before the log cabin remodel.Īfter the Rustic Cabin Manufactured Home Remodel The front exterior had already been updated with shingled vinyl siding and a new deck but the couple had a more traditional log cabin vision and they absolutely nailed it! ” My favorite room is probably the kitchen.”īefore the Rustic Cabin Manufactured Home Remodel.Rustic cabin Manufactured Home Remodel – Interior.After the Rustic Cabin Manufactured Home Remodel.Before the Rustic Cabin Manufactured Home Remodel. ![]() ![]() ![]() ![]() However, IUPAC recommends that the numbers 1 through 18 be used, and these labels are more common. In the United States, the labels traditionally were numerals with capital letters. Groups are labeled at the top of each column. The elements are arranged in seven horizontal rows, called periods or series, and 18 vertical columns, called groups. Each box represents an element and contains its atomic number, symbol, average atomic mass, and (sometimes) name. A modern periodic table arranges the elements in increasing order of their atomic numbers and groups atoms with similar properties in the same vertical column (Figure 2). The modern statement of this relationship, the periodic law, is as follows: the properties of the elements are periodic functions of their atomic numbers. (credit a: modification of work by Serge Lachinov credit b: modification of work by “Den fjättrade ankan”/Wikimedia Commons)īy the twentieth century, it became apparent that the periodic relationship involved atomic numbers rather than atomic masses. (a) Dimitri Mendeleev is widely credited with creating (b) the first periodic table of the elements. Although Mendeleev and Meyer had a long dispute over priority, Mendeleev’s contributions to the development of the periodic table are now more widely recognized (Figure 1).įigure 1. The discoveries of gallium (1875) and germanium (1886) provided great support for Mendeleev’s work. But Mendeleev went one step further than Meyer: He used his table to predict the existence of elements that would have the properties similar to aluminum and silicon, but were yet unknown. Both published tables with the elements arranged according to increasing atomic mass. Fluorine (F), chlorine (Cl), bromine (Br), and iodine (I) also exhibit similar properties to each other, but these properties are drastically different from those of any of the elements above.ĭimitri Mendeleev in Russia (1869) and Lothar Meyer in Germany (1870) independently recognized that there was a periodic relationship among the properties of the elements known at that time. For example: Li, Na, and K are much more reactive than are Ca, Sr, and Ba Li, Na, and K form compounds with oxygen in a ratio of two of their atoms to one oxygen atom, whereas Ca, Sr, and Ba form compounds with one of their atoms to one oxygen atom. However, the specific properties of these two groupings are notably different from each other. A second grouping includes calcium (Ca), strontium (Sr), and barium (Ba), which also are shiny, good conductors of heat and electricity, and have chemical properties in common. One such grouping includes lithium (Li), sodium (Na), and potassium (K): These elements all are shiny, conduct heat and electricity well, and have similar chemical properties. Identify metals, nonmetals, and metalloids by their properties and/or location on the periodic tableĪs early chemists worked to purify ores and discovered more elements, they realized that various elements could be grouped together by their similar chemical behaviors.Predict the general properties of elements based on their location within the periodic table.State the periodic law and explain the organization of elements in the periodic table.\)īy the end of this section, you will be able to: ![]() 2/29/2024 0 Comments Klondike solitaire 12 games![]() ![]() You play free FreeCell game by building these four Foundations up in ascending sequence (one suit in each), starting from Aces to kings. There are four cells called Foundations in the upper-right part of the board. ![]() After shuffling, a tableau is set up of a total of 52 cards, placed into eight columns row by row, so at the end first four rows contain seven cards and the last four contain six cards each. But for you to be able to do this there must be no empty columns (you can move any card of sequence to fill an empty column).Ī little more difficult free online solitaire, FreeCell (or Free Cell Solitaire) is played with one standard 52-card deck (no Joker). If you find yourself out of constructive moves you can click on the stock in the lower-right corner and deal a new card to every column on the tableau. In case you already have some emptied columns on the tableau you can also move any exposed card or same-suit descending sequence there. That's why it's always better to form sequences of the same suit if possible. You can also move a packed descending sequence of the same suit (they are highlighted for your convenience) as a group. You can move an exposed card to another column in the tableau if the movement creates a new continuous descending sequence (regardless of suit, so it's similar with Spider Solitaite 2 Suit, 1 Suit and 4 Suit). When all 104 cards are removed (as separate King to Ace sequences), you win the game. If a whole sequence is formed in one of the columns it is removed from the tableau completely. Your goal when playing Spider solitaire free online is to build stacks of cards on the tableau forming descending suit sequences (from King to Ace). The remaining cards are placed in the stock at the lower right of the layout (face down). In each column, all of the cards are placed face down except for the last one which is upturned. After shuffling, a tableau is set up of a total of 54 cards, placed into ten columns. There's also Spider Solitaire 2 Suit where two suits (e.g. One Suit Spider solitaire - also 104 cards but only one suit (e.g. ![]() But you can play solitaire online two other ways. This is called 4 Suit Spider solitaire and it's the most challenging variation. One of the moderately difficult solitaire games, Spider is played with two standard 52-card decks (no Jokers). So the aim of the Klondike free solitaire game is to eventually take apart all the tableau piles (and empty the stock) by transferring all cards into four stacks (called foundations) in the upper right part, each of the one suit, starting with Aces and ending with Kings. Once you emptied one of the piles completely you can start or move a new pile (or single card) here, starting with a King card. You can move a single card, a part of any pile or a complete pile on top of any other pile, but according to this rule - alternate colors and downwards order. Contrary to that the tableau piles are built down by alternate colors. Foundations are built up by suit, starting from Ace, then Two, Three and up to King. Your goal in free Klondike solitaire is to build the four foundations (in the rectangles in the upper right part). The remaining cards are placed in the stock at the upper left of the layout (face down). In each pile, all of the cards are placed face down except for the last one which is upturned. From left to right, each column contains one more card, so the first one contains just one card, the second one - two cards and so on. After shuffling, a tableau is set up with seven columns of cards. You play this free Klondike Solitaire with a standard 52-card deck (no Jokers). Probably the favorite free online solitaire among players. ![]() ![]() The fast-growing anti-drone industry involves wildly different approaches and technologies. Other hotspots for drone trouble include ports, borders, power stations, and special events.Īll these scenarios and incidents are driving an explosion in anti-drone technologies. Another problem is that drones make noise that can hamper search efforts. Such events involve fast-moving helicopters and other aircraft that are endangered by drones. Curious onlookers are using drones to check out fires, police standoffs and the damage caused by natural disasters. (Confession: I'm a big fan of the HD Apple spaceship campus videos.)įirst responders are increasingly harassed and endangered by drones. Celebrity-obsessed fans and paparazzi are increasingly buzzing movie and TV sets, such as The Game of Thrones set in Ireland.Ĭonstruction sites for splashy or secretive building projects get the drone treatment as well, sites like Apple's new spaceship campus in Cupertino, Calif. Unauthorized, unwanted or illegal drone flying is a growing problem all over the world. Companies like Airbus and Boeing are developing anti-drone technologies, presumably to be installed in the jets themselves. airports to deal with the drone menace.ĭrones have become such a central problem for airports that airplane makers are getting into the action. FAA rules say that drones are not allowed to fly above 400 feet.ĭenver International Airport last month started testing "drone zappers" as part of a wider effort by the FAA to identify the best way for all major U.S. It recently deployed a "drone hunter," a drone that uses an infrared camera to identify drones near the airport.Ī small private airplane flying about four miles from the Dallas-Fort Worth International Airport last month spotted a drone flying at an incredible 4,000-feet altitude. ![]() The Dubai airport was closed three times this year because of drones. Airport drone strikes and near strikes are way up. Although far less likely than bird strikes, drones are a growing concern. It's also why prisons around the world are weighing their options with anti-drone tech.Īirports also have a drone problem. That's why The UK's Ministry of Justice wants drone-makers to hard-code prison locations into consumer drones to make prisons into no-fly zones. In fact, with prison drone smuggling, they rarely are. (I guess he planned to saw his way out, then call an Uber.) Prison guards in Denmark last week discovered that someone used a drone to fly two mobile phones and a saw blade right through the window of a prisoner's cell. Accomplices on the outside are smuggling smartphones, drugs, and weapons using drones. Prisons worldwide have a big drone problem. Air Force wants handheld drone-killing kits.Įven as military contractors develop new tech to defeat drones large and small, the need for domestic, non-military, anti-drone tech is heating up. Marine Corps is working on a truck-mounted laser beam that kills smaller drones in flight. ![]() ![]() (Surprisingly, ISIS terrorists aren't just using off-the-shelf consumer drones, but also building their own from scratch.) And these smaller drones need a smaller solution. But insurgents, terrorists and criminals are increasingly flying smaller, consumer-sized drones for delivering bombs. Trouble is, big-iron solutions are right for the airplane-sized drones used by major military powers. I want one, but it's probably out of my league. ![]() It's essentially a microwave radiation transmitter mounted on a 20-foot shipping container. Army is testing Raytheon's Phaser, a massive electromagnetic pulse (EMP) device that can shut down an entire drone swarm with a single blast. The big military contractors, like Boeing, Lockheed Martin, Raytheon, Thales Group, Israel Aerospace Industries and Russia's United Instrument Manufacturing Corporation (which focuses on countering U.S.-made military drones) were happy to develop expensive, powerful anti-drone technologies. The anti-drone idea started years ago with the military. ![]() 2/29/2024 0 Comments Free and printable sudoku puzzles![]() ![]() ![]() If you love these printable brain teasers and you’re looking for more printable games and puzzles then check out our printable word searches and printable crossword puzzles. A challenging puzzle helps you work your brain and use your skills better. Some puzzles are going to challenge you, but that’s a good thing. ![]() If you’re stuck, simply use trial and error to complete the puzzle. Sudoku isn’t about guessing, it’s about logic and numbers. If all of the other cells in a row or column are filled up then the empty cell will be the number that isn’t already there. You will find these if you start by looking at any rows or columns that are near completion. The best way to start a sudoku puzzle is to look for the empty cells that can only contain a certain number. Use a pencil and write lightly and small or use our blank sudoku grid to write your digits down. There’s going to be a point when you need to write down the numbers to figure out your puzzle. Move on to the next difficulty when you feel like you need a new challege. It takes time and skill to complete a Sudoku puzzle and practice makes perfect. If you’re new to sudoku then check out these simple tips to help you on your way: Filling each row and column will allow you to fill the grid but the difficulty lies in the empty cells.Įach sudoku puzzle has allocated numbers on the grid that are clues to help you find what digits are missing in each row or column.Įvery 9×9 box on the grid should contain the numbers 1 to 9 without any duplicates. The aim of the game is to fill each row in the grid with the numbers one to nine without any duplicate numbers. Take a look at these sudoku rules and tips and you’ll be ready to play sudoku in no time. When you understand the rules of sudoku the game becomes pretty straightforward. Starting with these easy puzzles will help you practice Sudoku and get better. These easy sudoku printables are perfect for beginners. Simply click on each printable image and save it to your computer before printing. Free printable sudoku puzzles to print and play online. If I can complete a sudoku puzzle, then you definitely can too! And if you need some advice then you can find helpful sudoku tips at the bottom of this page. These patterns are crucial to solving the puzzle, so you must pay attention to them. In high school, I wasn’t very good at math or working with numbers, but these puzzles are something I totally love and with a little practice I actually became good at sudoku. If you’re new to sudoku don’t let the look of these puzzles intimidate you. In this post, you’ll find free printable sudoku puzzles along with rules and tips for successful puzzle solving. Whether you’re a new sudoku player or a skilled veteran, we have over 100 printable sudoku puzzles from easy to hard for you to enjoy.Ĭure your boredom with these great logic puzzles and sharpen your logic skills! Simply choose your difficulty level from our selection – easy, medium, hard, and very hard – and put your brain to the test. ![]() |
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